The NiCl2‐Li‐Arene (cat.) Combination as Reducing System, Part 9: Catalytic Hydrogenation of Organic Compounds using the NiCl2‐Li‐(Naphthalene or Polymer‐Supported Naphthalene) (cat.) Combination
Identifieur interne : 000509 ( Main/Exploration ); précédent : 000508; suivant : 000510The NiCl2‐Li‐Arene (cat.) Combination as Reducing System, Part 9: Catalytic Hydrogenation of Organic Compounds using the NiCl2‐Li‐(Naphthalene or Polymer‐Supported Naphthalene) (cat.) Combination
Auteurs : Francisco Alonso ; Pablo Candela ; Cecilia G Mez ; Miguel Yus [Espagne]Source :
- Advanced Synthesis & Catalysis [ 1615-4150 ] ; 2003-01.
English descriptors
Abstract
The reaction of lithium powder, a catalytic amount of naphthalene or polymer‐supported naphthalene, and anhydrous nickel(II) chloride, in THF at room temperature, generates a finely divided and very reactive nickel(0) which has been efficiently applied to the catalytic hydrogenation of different organic compounds such as alkenes, alkynes, carbonyl compounds, imines, organic halides, aromatic compounds, hydrazines, azoxy compounds, and N‐oxides.
Url:
DOI: 10.1002/adsc.200390022
Affiliations:
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<front><div type="abstract" xml:lang="en">The reaction of lithium powder, a catalytic amount of naphthalene or polymer‐supported naphthalene, and anhydrous nickel(II) chloride, in THF at room temperature, generates a finely divided and very reactive nickel(0) which has been efficiently applied to the catalytic hydrogenation of different organic compounds such as alkenes, alkynes, carbonyl compounds, imines, organic halides, aromatic compounds, hydrazines, azoxy compounds, and N‐oxides.</div>
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