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The NiCl2‐Li‐Arene (cat.) Combination as Reducing System, Part 9: Catalytic Hydrogenation of Organic Compounds using the NiCl2‐Li‐(Naphthalene or Polymer‐Supported Naphthalene) (cat.) Combination

Identifieur interne : 000509 ( Main/Exploration ); précédent : 000508; suivant : 000510

The NiCl2‐Li‐Arene (cat.) Combination as Reducing System, Part 9: Catalytic Hydrogenation of Organic Compounds using the NiCl2‐Li‐(Naphthalene or Polymer‐Supported Naphthalene) (cat.) Combination

Auteurs : Francisco Alonso ; Pablo Candela ; Cecilia G Mez ; Miguel Yus [Espagne]

Source :

RBID : ISTEX:86751AC1E61BB69FB01BE0AF60EECECE6AB342B7

English descriptors

Abstract

The reaction of lithium powder, a catalytic amount of naphthalene or polymer‐supported naphthalene, and anhydrous nickel(II) chloride, in THF at room temperature, generates a finely divided and very reactive nickel(0) which has been efficiently applied to the catalytic hydrogenation of different organic compounds such as alkenes, alkynes, carbonyl compounds, imines, organic halides, aromatic compounds, hydrazines, azoxy compounds, and N‐oxides.

Url:
DOI: 10.1002/adsc.200390022


Affiliations:


Links toward previous steps (curation, corpus...)


Le document en format XML

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<div type="abstract" xml:lang="en">The reaction of lithium powder, a catalytic amount of naphthalene or polymer‐supported naphthalene, and anhydrous nickel(II) chloride, in THF at room temperature, generates a finely divided and very reactive nickel(0) which has been efficiently applied to the catalytic hydrogenation of different organic compounds such as alkenes, alkynes, carbonyl compounds, imines, organic halides, aromatic compounds, hydrazines, azoxy compounds, and N‐oxides.</div>
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